Global Demand for Silica

Silica is a chemical compound in different forms, like sand, soil, quartz, and crystalline silica. It is the major ingredient in many industries. And sometimes, it is also found in the human body at a low or high level. A wide range of silica producers and consumers with various consulting engagement results in increased global demand for silica.

Silica occurs in nature in the form of crystalline silica, also known as quartz. This crystalline silica is extraordinarily sharp and fragile. When these crystals shatter, they actually fragment into tiny dust particles, which easily get into the body of humans or animals while respiration. The smaller the fragments produced, the more threat it will be, to the environment and living things around. 

Some of the important uses of silica are:

  • Production of glasses
  • For Sandblasting and making sandpaper 
  • Various types of dishes like glasses and cups.
  • Adhesives glue 
  • Production of many toothpastes 

Silica sand, generally called industrial sand, is the main common variety globally. It was mining for many years and was first put to industrial use even during 3000-5000 BC for metallurgical and glass-making activities.

The key factors driving the global demand for silica :

The increasing uses of silica sand in paving roads, glass making, foundries and coal burning boilers, oil and water filtration, industrial casting, sandblasting, etc., is now catalyzing the global silica sand market.

Additionally, it has an important application in the hydraulic fracturing, where the order for silica sand is increasing significantly in recent years. This can be certified to the profitable qualities of silica sand, like strength, high silica content, and resistance to heat and chemical reactions.

Khaitan Responsibly sources silica sand to meet global demand

Global stocks of silica sand are being used up rapidly than they are being discovered. As the main ingredient for all glass and concrete, silica sand is the basic ingredient of today’s world. The UN estimates that the world currently uses 50 billion tonnes or more of it to construct a wall 27m wide and 27m high around the planet – every year.we extract Silica as a high value byeproduct and valorize lignin to generate steam. This is a major breakthrough in establishing commercial viability for the technology and compete with ethanol produced from other sources.

Oil and gas industries fuel silica markets

Silica consists of the earth crust’s most abundant elements: silicon and oxygen. Silica has various crystalline forms, such as fibrous, granular, anhydrous, tridymite, cristobalite, and quartz. Quartz is the next most mineral found in the earth’s crust.  

Silica deposits undergo extensive processing before the sale, including cleaning, washing, scrubbing, melting, and grinding to remove impurities and to produce the ideal size distribution of product depending upon end–use. Silica has many end-users and applications across various industries.   

The energy sector is one where increased exploration and production for oil and gas have increased the demand for silica used in the past decade. In hydraulic fracturing, it is widely used as a proppant to hold open fractures to allow oil and gas. Also to flow out of the production and into the excellent bore. Figure 1 shows the United States consumed 100 million tons of industrial sand and gravel in 2017, an increase of 33% from the previous year. This increase was primarily due to increased activity in the oil and gas industry. 

Figure 1: End-uses of silica sand consumption in 2017.

 

In addition to hydraulic fracturing for oil and gas production, silica serves in many other industries too. Depending upon the types of silica, the uses varies. Following are the few of the major applications  

  • Glass: glass containers, flat glass, automotive glass, fibreglass, and speciality glass 
  • Construction: flooring, roofing, mortars, and speciality blocks of cement 
  • Ceramics: glossier products and applications that need good thermal resistance
  • Foundries: highway and construction use, aggregate substitutes, and manufactured soils
  • Chemicals: Polymers, personal care products, industrial cleaners, fibre optics 

Global Silica Sand Industry Drivers:

  • The glass market is facing high growth as a result of increased demand from the construction industry, increasing automotive production or sales, mounting per capita income, and technological improvements. Along this, rising trends such as increasing usage of the hybrid guide plate, solar powered glazing for automotive and building glasses, flimsy glazing glass, and new launch of flat glass are also contributing towards the extension of of the glass industry boosting the demand for silica sand.
  • Several countries worldwide prefer natural shale gas to reduce their dependence on crude oil. In Shale gas extraction using the hydraulic fracturing process where silica sand is the proppant. As a result, the growth in shale gas production is a reason to widen the demand for silica sand. 
  • Upcoming industrial projects in different nations expects to accelerate the manufacturing industry, thereby adding up the need for silica across different sections. Tour Triangle and the ASVEL arena(France) are forecasted to support the silica sand market growth.

 

Key Market Segmentation:

Based on end-use, the record discovers that the glass industry considers more than a third of the total market, constituting the largest end-use sector. Silica sand is essential in producing glass containers, flat glass, and speciality glass that further use in automotive, construction and solar applications. The glass industry followed by foundry, hydraulic fracturing, filtration, and abrasives.

Regional Insights:

  • China
  • United States
  • Italy
  • Turkey
  • Germany
  • Australia
  • Others

Region-wise, the China enjoys the leading position in the global silica sand market. China is followed by United States, Italy, Turkey, Germany, Australia and Others.

With such vast uses of silica in various industries, silica demand continues to increase globally. Each of these applications requires silica with a specific set of properties and compositional requirements.

World Energy Day

The first World Energy Day was on July 11 of 1924. Over 1700 experts from 40 countries marked that energy issues can influence growth and the future of mankind and accept that a permanent world energy organization should be established. It is celebrated world wide to make sure access to economical, reliable and contemporary energy for all by 2030. It is marks the important role in leading economic growth, human development and environmental sustainability.

In 2012 World Energy was created by the World Energy Forum and has been celebrated each year since October 22. The objectives of World Energy Day are to raise awareness about energy usage and ensure the safe and green energy for all people. It also targets on reducing carbon emission .

It aims to raise awareness of the importance of saving natural resources for climate change, environmental protection, and sustainability. All these elements contribute to increasing energy sustainability and efficiency.

The 2022 motto is “Energy transition – full speed ahead!”. This will include discussions on the far reaching transformation of policies and technologies for achieving climate neutrality and how to raise the pace of change. Thus World Energy Day aims to raise the importance of saving our natural resources for sustainability. All these contribute to increase energy efficiency as of the report from Sub-Saharan Africa.Here most of the people gains access to electric power has begun to outrun population growth recently.

The main objectives of World Energy Day

From the beginning, World Energy Day was a good chance to raise awareness about the importance of saving natural resources. Eventually, topics like sustainability, climate change, conservation and efficiency are all part of this ongoing conversation. But energy access for all has taken on an important priority since an estimated 900+ million are living without energy access today.

Ensuring the affordability of sustainable energy for everyone by identifying the need for developing national policies to consider a shared global energy perspective. The objectives also strengthen policies to execute and develop mechanisms to exchange experience between various countries through the world. This includes encouraging the development of resources to run after the common good of everyone by continuing the wise use of fossil fuels in the world economy.

Energy efficiency and its importance

Saving energy, improving efficiency, and conservation are the factors use to explain ways we can lower our overall energy consumption. There are several reasons why we would do this in order to use energy most efficiently:

  • Lower the cost of energy 
  • Reduce the threat to the environment and thus save our natural resources
  • The worst predicted influence of climate change are about to happen — and much faster than climatologist expected. Climate change is the major problem,but there’s a lot we should do about it in our day to day life. Individual actions to lower greenhouse gas emissions can help reduce climate change.

An international lead for universal energy access

Innovations in decentralize energy systems permits the problem of energy access to notify. The IEA report states the people without access to electric power fell to 1.1 billion down from 1.6 billion. Now a days India is leading , focussing to reach complete electrification 10 years than the target set under the UN Sustainable Development Goals .

West makes the conversion from fossil fuels to renewable energy, an estimated 1.1 billion people through out the world. But the most of them in sub-Saharan Africa, are without access to electricity still. To spot this day, KhaitanBioEnergy look at the needs to be done in investment of technology to make universal access to energy a reality.

How can we achieve it? 

Developed countries have not observed consistent and reliable electricity a luxury for some time now. With many observing consistent electricity, it is an intolerable fact that there remain areas with irregular access to electricity. Reliable energy is the main driver of human progress. Acquiring electricity makes communities guarded, helps small businesses survive and even flourish.Also powers necessary services such as schools and clinics.

 By providing a good environment for investments, innovations and new industries that incentivize growth and provide jobs for developing economies. The government’s immense efforts over the last decades have put it on of the main success stories ever in electrification.

Subsequently, authorities have used solar, energy storage batteries and LED lighting to supply 80% of previously unconnected villages with power.

Some countries are still without electricity.

The IEA estimates that supplying electricity for all by 2030 will need an annual investment of $52 billion. The extra investment, 95% needs to be spent to sub-Saharan Africa. South Sudan with the least level of electricity access in the world. Utility organisations in developing countries often cannot pay for to hook small, scattered rural communities up to the grid. Same way, high connection costs for informal housing and the effect of power theft on services are unaccompanied by electricity.

About 110 million of the 600 million people living without access to electicity in Africa . In Kenya, approximately 70% of off-grid homes are within just 1.2 KM of a power line.

Moreover, even in resource-rich Europe, the European Union (EU) about 50 million people lack from energy , whereas they hardly heat their homes and finds utility bills in time.

Can renewable energy sufficient for energy gap?

Of the 1.2 billion people have gained access to electricity since 2000, nearly all have done so via connection to the main grid, with 70% getting access to power generated from fossil fuels . Recently the number of people gaining access to electric power in Sub-Saharan Africa starts to outrun population growth.

However declining costs for solar power, decentralized solutions, off-grid and mini-grid systems etc results electrifying sub-Saharan Africa that helps to achieve with clean energy.

Nowadays, renewables have been the source of over one-third of new connections, while decentralized renewables are the source of 6% of new electricity access.

The World Energy Council expects solar and wind to rise from 4% globally in 2016 to 42% in 2060. Moreover, renewables have provided more than a third , IEA expects this shift to accelerate by 2030. It should be noted that providing energy access for all would not result in a net increase in global greenhouse gas emissions. Energy demand and related CO2 emissions would only increase by around 0.2%. This would be more than offset by net GHG reductions resulting from reduced use of biomass for cooking.

Achieving universal energy access

The solution to electrifying detached communities lies in the deployment of decentralized and renewable energy sources. Mini- and off-grid systems provide communities agency over their energy utilization and independence from the main grid, while renewables are becoming highly inexpensive and thus more viable for smaller, developing sites.

Increased investment into these technologies is integral to currently unelectrified homes receiving affordable and reliable power. According to the IEA report, universal electrification would require an annual investment of $52bn, representing more than twice the level mobilized under present norms. 

Of the additional investment, 95% needs to focus on sub-Saharan Africa. Detail geospatial modelling suggests that decentralized systems, led by solar photovoltaic in off-grid systems and mini-grids, are the cheapest method for 3 quarters of the extra connections needed in sub-Saharan Africa.

About a $350m electrification program in Nigeria is expected to attract $410m in private investment and create a market for mini and off-grid energy solutions. Based on this scheme, the Nigerian Rural Electrification Agency is mapping more than 200 sites for mini-grid development.

The extreme global temperatures and weather conditions caused by climate change have led nations across the world to step up clean energy efforts. With technological innovations causing prices of solutions such as wind and solar to dip and installations to soar. However, despite renewables’ growing grasp of the energy market, the industry still faces the problem of universal energy access.

To mark World Energy Day, KhaitanBioEnergy looks at global energy access and the measures underway to improve it. However, authorities need to do much more work if the target of universal electrification is to be obtain by 2030.

On this World Energy Day, let’s pledge to help build a sustainable future for the future generations . India provides a key example of a nation working to rapidly electrify. The Modi government pledged to electrify every home in the region by December 31 2018, under an INR163 bn (US$2.5bn) scheme known as ‘Saubhagya Yojana. Since then, authorities have supplied 80% of previously unconnected villages with power, using solar energy storage batteries and LED lighting.

H2, EV and Biofuel

The automobile industry is a core sector with inspiring success stories. The automobile industry’s estimated annual production is 22.93 million in FY 2022. It contributes 49% of India’s manufacturing GDP and 7.5 per cent to the country’s GDP. Further, Automotive manufacturers are seeking alternative methods to power cars and other vehicles to reduce carbon emissions and fossil fuel use. Such initiatives have driven the industry to launch vehicles adapted to biofuel, electricity, and Hydrogen.

What to know about 3 types of Fuel Alternatives

Resources like water, natural gas, fossil fuels, or biomass are the traditional raw materials for fueling a vehicle, which is now in limited supply. However, hydrogen is the most abundant element in the universe. Hence, Hydrogen cars (FCEVs) are those cars that have characteristics of both electric vehicles and conventional petrol cars. These cars produce electricity by allowing hydrogen to react with oxygen to create the chemical production of electricity and water vapour. Hydrogen cars are much faster to refuel than electric cars, reducing atmospheric pollutants’ emissions.

Electric vehicles (BEVs) are either partially or fully powered by electric power. EVs run on a lithium-ion battery, charged by plugging into a socket or any other charging unit. They are eco-friendly vehicles that can accelerate faster than vehicles with traditional fuel engines. Moreover, they are cheaper, noiseless engines that produce no exhaust fumes and are more reliable than hydrogen-powered vehicles. Globally, the Government have been investing in infrastructure for electric cars. There is widespread availability of charging stations in petrol pumps, motorway rest stops, shopping centres and even on specific streets for convivence and ease of access.

Biofuel is a renewable energy source from organic matter like wood, straw, sludge, sewage, vegetable oil, etc. It helps maintain a healthier and cleaner environment since there is no emission of hazardous gases, such as Carbon monoxide (CO) or Sulphur oxide (SO), thereby reducing the risk of global warming. Biofuel can be classified into first, second, and third generations based on their feedstock and production technology.

Differences between H2 and EV

Range

Hydrogen vehicles offer a higher range and faster refuelling when compared to electric vehicles. For, e.g. the Hyundai Nexo can manage 414 miles and only takes five minutes to fill up. The range of EVs is highly dependent on their vehicle. For instance, expensive cars like Tesla Model S have a range of 375 miles compared to a real-world range of 150 miles for the less expensive Nissan Leaf Acenta.

Availability of Charging/Refuelling Station

Hydrogen cars have less infrastructure, with only around 400 refuelling stations across the globe. Currently, In comparison, EVs have thousands of charging stations worldwide.

Cost of Ownership

Currently hydrogen cars are costly, with no affordable options in the market. But overall expense of FCEV’s can be lesser in comparison to BEV’s. On the other hand, the cost of an EV depends on the model and manufacturer.

Safety

Hydrogen is a safer alternative than conventional fuels in a multitude of aspects. Also, hydrogen is non-toxic, unlike traditional fuels. But safety concerns are still based on its flammable nature when stored in bulk. Electric vehicles have insulated high-voltage lines and safety features that deactivate the electrical system when they detect a collision or short circuit. All-electric cars tend to have a lower centre of gravity than conventional vehicles, making them more stable and less likely to roll over.

Emissions

Many conventional fuels are toxic or contain poisonous substances. These include potent carcinogens responsible for the increased risk of human cancer cell growth. But there are no greenhouse gas emissions from hydrogen. In the case of EVs, it has zero tailpipe emission as it runs on electricity.

Difference Between EV and Biofuel

Maintenance

An electric vehicle with no friction between moving parts or exchanges between liquids and gases needs neither lubricant nor exhaust. Stationary fuel cells, in particular, need very little maintenance, with servicing required once every one to three years.

Emissions

Though electric vehicles are not 100% green, they produce a fraction of the greenhouse gases and waste that a combustion engine car does. They even compared it to biofuel vehicles. The only greenhouse gases produced are in the actual manufacturing of the car and the emissions produced from the power plants supplying electricity to your home where your car vehicle is plugged in.

Limitations

The downsides are that there is a strict limit to how many miles can be traveled in a day on a full charge before needing to recharge. With biofuels, there is no limit since you can refuel in seconds compared to hours with an electric vehicle.

Availability & Accessibility

Biofuels are a renewable energy source. Because biofuels are derived from plant matter (and occasionally animal matter) that can be harvested annually or, in the case of algae, monthly, biofuels are theoretically unlimited. But in India, biofuel blending can only thrive as a fuel when it has a necessary infrastructure facility for extraction, production and distribution. However, the Union minister of India has addressed the necessity of flex-fuel vehicles and imposed a mandatory option towards automakers to offer cars that run on 100% biofuels within a few months. Electric vehicles are more accessible due to government policies to boost e-mobility and thus promote the development of a charging infrastructure network. There are currently over 10,76,420 electric vehicles and 1,742 Public Charging Stations (PCS) operational in the country.

Cost

Biofuel adaptive vehicles, also known as flex-fuel vehicles, are currently a concept but can be a real deal after a few months. Thus, the fuel price of bioethanol, a type of biofuel, would be Rs. 65 against the current petrol price of Rs.110. In contrast, electric cars in India, priced accordingly, include Tata Tiago EV (₹ 8.49 Lakh), Tata Nexon EV (₹ 14.99 Lakh) and Mercedes-Benz EQS (₹ 1.55+ Crore). Electric two-wheelers are priced from 50,000 to 2 Lakh.

Difference Between H2 and Biofuel

Emission

Hydrogen, after processing, generates electrical power in a fuel cell, emitting only water vapour and warm air. It holds promise for growth in both the stationary and transportation energy sectors. Emissions from biofuel, such as Carbon dioxide, carbon monoxide, sulfur dioxide, particulate matter and other hydrocarbons, are much less than conventional fuel.

Pricing

Hydrogen is cheap, and its combustion produces only water (no CO2). It has three times as much energy as an equivalent quantity of petrol. Current green hydrogen production costs range anywhere between ₹320 and ₹330 per kilogram in India. It can reduce to as low as ₹160-170 per kg by 2030, bringing parity with grey hydrogen and other fossil fuels. But hydrogen contains less energy per unit volume than all other fuels. Transporting, storing, and delivering it to the end-use point is more expensive per gasoline gallon. The average price of ethanol and biodiesel in India is Rs.70 per litre. However, there is a substantial difference in these prices among countries as well as states.

Potential

The transport sector, railways, and aviation is the major end-user of biodiesel, and bioethanol. It can also be found in automobiles, energy production, the chemical industry, etc. However, bioethanol production from fourth-generation feedstock is still in the embryonic stage. With India’s prime energy demand is to be doubled by 2040 and thus the demand of biofuel would increase as a result.

Based on FY 2021- quarterly update, India’s biodiesel market demand stood at 0.17 million tonnes despite major setbacks due to the pandemic induced disruption in supply chains. The report predicted a healthy growth of 8.60 per cent CAGR until 2030, with a forecasted demand set to reach 0.26 million tonnes. Also, for hydrogen induced fuel showcases similar growth potential as the cumulative value of the green hydrogen market in India could be $8 billion by 2030 and $340 billion by 2050. Electrolyser market size could be approximately $5 billion by 2030 and $31 billion by 2050.

Storage

Hydrogen is difficult to store due to its low volumetric energy density. It is the lightest of all elements, more delicate than helium, and quickly lost into the atmosphere. The onboard hydrogen storage systems expense is too high, particularly in comparison with conventional storage systems for petroleum fuels.

But in contrast, the storage of pure biodiesel from vegetable oil is to be safely kept at 45° to 50°F. In cold climates, Above-ground tanks may need to be heated or insulated, depending on the location. Also, biodiesel should not be stored or transported in copper, brass, bronze, lead, tin, or zinc because these metals will hasten degradation. If biodiesel is held for about four to five months, a stability additive to be used, especially in more southern climates due to increased temperature and humidity. Ethanol also tends to absorb water from the surrounding environment—stored in dry areas with low humidity. Ethanol will absorb any condensation that forms inside storage vessels.

Availability

The biomass feedstock required for biofuel are more expensive than petroleum. Also the processes for producing the fuel aren’t yet efficient enough to produce it very cheaply. But as of current scenarios in the year 2021, The United States was the leading biofuel producer in the world, with production amounting to 1,436 petajoules. Brazil and Indonesia ranked second and third, with figures at roughly 840 and 312 petajoules, respectively. By comparison, Germany’s biofuel production reached around 121 petajoules, placing the country amongst the top five countries in biofuel production, and the leading producer in Europe.

Synthetic fuel

What is synthetic fuel

What is synthetic fuel?

A liquid fuel not from natural crude oil is a synthetic fuel, and synthetic fuels are artificial alternatives to conventional gasoline or diesel. In its simplest form, a synthetic fuel combines hydrogen and carbon atoms to form a compound known as an alkene — usually Ethene, which consists two carbon atoms and four hydrogen atoms.

Nevertheless, there is much variance in how individual companies go about obtaining to an end product that could be pump into the fuel tank of vehicles. Some synthetic fuels use mind-bending chemical processes, and others start as a literal load of old garbage.

 Modern transportation fuels demand uniform physical properties from varying feedstocks with chemical compositions mainly synthesized from petroleum or other fossil fuels

 The term gasoline implies that many components are synthesizing using cracking or reforming techniques. Thus, gasoline is rather than synthetic fuel, and reformulate gasoline contains a more significant fraction of petroleum molecules. 

Fuels from oil sands and heavy oil come under the same term as petroleum-based fuels. Liquid fuels from coal, peat, natural gas, and oil shale are synthetic fuels. Renewable biomass from photosynthesis gets converted into a variety of synthetic fuels. Coal gasification and natural gas reforming are sources of synthesis gas. That is a mixture of hydrogen and carbon monoxide(CO), the essentials for producing synthetic fuels.

How is it made?

  Independent of origin, Ethanol, methanol, and biodiesel comes under the term synthetic fuel. Coal gasification and natural gas reforming are sources of synthesis gas, a mixture of hydrogen and carbon monoxide.

To understand the manufacturing of renewable synthetic fuels, firstly, you must understand what fossil fuels are. They consist of a large number of various hydrocarbon molecules.

The key to component synthetic fuels is syngas. Syngas is a mixture of hydrogen (H) and carbon monoxide, and it is essential to produce liquid hydrocarbon fuel like jet fuel, diesel, or gasoline. Turning syngas into fuel is a confirmed industrial process, using coal and natural gas as feedstocks, which is not sustainable. So that is precisely where the challenge lies: producing sustainable syngas. This production requires a large amount of energy, and to produce it sustainably, it needs to come from a renewable resource like biomass, solar, wind or hydro.

Synthetic fuels can be created via several different processes. One of these processes is coal liquefaction. Usually, this process generates large amounts of carbon dioxide, making it a wrong alternative to conventional fuels.

However, it is also possible to create synthetic fuels through a method that captures carbon dioxide from the atmosphere. This technique is receiving appreciation and investment from car makers and other industries.

The process works like this:

  1. Obtain Carbon dioxide either directly from the atmosphere or industrial plants. Various methods exist for these processes.
  2. Renewable energy sources are avail to produce hydrogen. This can use to power hydrogen cars. 
  3. Then, hydrogen and carbon dioxide combine into synthetic methanol, which can then be convert into synthetic petrol and diesel.

 

Process :

The processes used to generate synthetic fuels broadly fall into three divisions: Indirect, Direct and Biofuel processes.

Indirect conversion

This type of conversion has the broadest deployment worldwide. About 260,000 barrels per day are produced by this method.

Indirect conversion broadly attributes to a step in which biomass, coal or natural gas converts to syngas through gasification or steam methane reformation. Then the syngas undergoes many processes and then converted into a liquid transportation fuel using any conversion techniques depending on the end product.

Indirect conversion synthetic fuels processes.jpg

The primary technologies that produce synthetic fuel from syngas are Fischer–Tropsch synthesis and process is Methanol-To-Gasoline conversion( MTG). In the Fischer–Tropsch process, syngas act in the presence of a catalyst, transforming into liquid products and potential waxes.

The process of generating synfuels through indirect conversion is coal-to-liquids (CTL), gas-to-liquid (GTL) or (BTL), depending on the initial feedstock. Some projects combine coal and biomass feedstocks, creating hybrid-feedstock synthetic fuels called Coal and Biomass To Liquids (CBTL).

Indirect conversion process technologies are available to produce hydrogen, mainly for use in fuel cell vehicles, either as a slipstream co-product or as a primary output.

 

Direct conversion 

Direct conversion means coal or biomass feedstocks converts straightly into intermediate or final products, thus avoiding conversion to syngas via gasification. These conversion processes are of two different methods: Pyrolysis & carbonization and hydrogenation.

Biofuel processes

One example of a Biofuel-based synthetic fuel process is Hydrotreated Renewable Jet (HRJ) fuel. There are different types of these processes under development, testing and certification process for HRJ aviation fuels is beginning.

There are two such processes. One using solid biomass feedstocks and one using bio oil and fats. The process uses solid second-generation biomass sources like grass or woody biomass. It then uses pyrolysis to produce a bio-oil, which undergoes stabilization and deoxygenation to produce jet-range fuel. The process then undergoes deoxygenation, followed by hydrocracking and isomerization to produce jet fuel.

The primary source of synthetic fuel

Generally, there are three methods for the production of renewable syngas. Furthermore, eventually, eco-friendly synthetic fuels are known as biofuels. These are mainly from biomass, e fuels- produced with renewable electricity, and solar fuels- manufactured with solar heat. All three methods mainly go through syngas, a combination of hydrogen and carbon monoxide. The syngas then turns into liquid fuels via industrial gas-to-liquid processes. These three methods are called Biomass-to-Liquid, Power-to-Liquid, and Sun-to-Liquid, respectively.

Biomass-to-Liquid produces biofuels

Even though several processes exist to change biomass into liquid fuels, the most scalable and versatile in terms of feedstock unergoes the gasification of biomass. Specifically, biomass changes at high temperatures into syngas. The heat input needed to drive the process is usually created by burning a part of the biomass. Feedstocks can be crops such as sugar cane, corn waste(stubble) biomass, or algae. Biofuels are the only form of renewable synthetic fuels that are readily available on the market in small quantities. 

Even though several processes exist to convert biomass into liquid fuels, the most scalable and most versatile in terms of feed stock goes through the gasification of biomass. Specifically biomass converts at high temperatures into syngas. The heat input require to drive the process is usually generated by burning a part of the biomass itself. Feedstocks can be any crops such as sugar cane or corn waste(stubble) biomass or algae. Biofuels are the only type of renewable synthetic fuels that are already available on the market in small quantities.

Power-to-Liquid produces e-fuels

E-fuels are produced from renewable powers such as solar, wind, or hydro power. The Power-to-Liquid process depends on a series of energy conversion steps. Firstly renewable electricity is generated which then drives an electrolyzer that splits water in hydrogen and oxygen. Next, the hydrogen is mixed with carbon dioxide and turned into syngas via the reverse water gas shift (RWGS) reaction .It is a process that conducts at high temperatures and driven with electricity. E-fuels can be produced with any type of renewable electricity. However, electricity storage for continuous operation remains a challenge.Hence it limits the application to few regions with an extraordinarily cheap and continuous renewable electricity supply .On the other hand it requires the integration of expensive battery technology for its working.

Sun-to-Liquid produces solar fuels

Solar fuels obtaining from solar heat that drives a thermochemical reactor. In this reactor, carbon dioxide and water are convers to syngas. Just like e-fuels, solar fuels are not yet available on the market. Sunny regions offer ideal conditions for the production of solar fuels, mainly deserts and semi-arid regions with high solar radiation. The solar heat during the day can store by inexpensive thermal energy storage to enable energy cycle of the production of fuels. Storage makes solar fuel plants self-sufficient and independent from any framework.

Why synthetic fuel necessary in future energy systems

It is clear that the benefits to energy systems from the stores of fossil fuel-based energy will not be able to replace without some other form of fuel-based energy storage. All energy systems have benefited from the stored chemical energy intrinsic in fossil fuels that has allowed a decoupling of primary energy supplies from the final use demand on a grand scale. Despite the fact that synthetic fuels are expensive, if policy makers wish to encourage them to grow in market share, then they could consider providing protected markets for them to compete within. Also to provide subsidies, or by costing fossil fuels with a carbon price that helps to close the cost gap.

The creation of synthetic fuels also provides a highly dispatchable demand to help integrate greater levels of weather-dependent renewables, which will be increasingly desirable in future energy systems that rely on primary electricity from renewables to a much greater degree.

The question simply put is not whether we will continue to need fuels in future energy systems, but the type of fuels that will be suitable in a highly eco-friendly.

Flex Fuel Engines

Flex fuel engines have an injection system that can operate with gasoline, with any mixture ratio of gasoline and ethanol, or with pure ethanol. Which means they are capable of running on 100% petrol or 100% bio-ethanol or a combination of both. Regardless of the supply, customers are supple when it comes to the choice of fuel and are able to respond to possible price developments immediately. Clearly flexibility with the choice of fuel is the key argument for buying vehicles with flex fuel engines. The market share of such flex fuel engines are high while other markets still show great potential to establish those systems. The main advantages of Flex Fuel Engines for Your Vehicle is resource saving mobility with ethanol as fuel. Flex Fuel Strong Hybrid Electric Vehicles (FFSHEV) basically houses an electric motor which powers the vehicle alongside the traditional petrol engine.

Dual fuel vehicle means the engine that uses two fuels (gas and diesel) together. Bi Fuel means the engine could run on either fuel but separately. On the other hand FFV is capable of running on either petrol or ethanol or a combination of both. Hence it is a combination of Dual fuel vehicle and Bi fuel vehicle.

How do flex fuel engines work using ethanol?

A flex fuel car looks just like any other kind of car. The main differences between the two lie with the engine and fuel system. Flex-fuels vehicles can run on regular gas, various ethanol blends and other types of fuel . Production of ethanol is mainly by fermenting agricultural residues. The main ethanol blends on the market today are E85 and E95, which get their names from their compositions. E85 is 15 percent unleaded gas and up to 85 percent ethanol . While E95 typically used in diesel powered vehicles is up to 95 percent ethanol. An engine that runs on regular petrol can also run on flex fuel which means any car with the spark-ignition engine can run on this flex fuel .

Components that comprise the fueling system of flex fuel vehicles are also crafted to be ethanol compatible. Otherwise higher water content of ethanol could cause rust to form and damage the fuel system from the inside out. Despite these different components, maintenance costs for FFVs are generally the same as for other vehicles, and sometimes are even lower, since flex fuels burn fuel more cleanly .

Comparison of flex fuel Vs gasoline vehicles

Apart from few differences, a flex fuel engine and a gasoline car have almost similar components.

Flex Fuel Engine

  • Battery: The battery provides electricity to start the engine and power vehicle electronics/accessories.  
  • Electronic control module (ECM): The ECM controls the fuel mixture, ignition timing, and emissions system; monitors the operation of the vehicle; safeguards the engine from abuse; and detects and troubleshoots problems.    
  • Exhaust system: The exhaust system channels the exhaust gases from the engine out through the tailpipe. There is a 3 way catalyst to reduce engine-out emissions within the exhaust system. 
  • Fuel filler: A nozzle from a fuel dispenser attaches to the receptacle on the vehicle to fill the tank. 
  • Fuel injection system: This system introduces fuel into the engine’s combustion chambers for ignition.        
  • Fuel line: A metal tube or flexible hose (or a combination of these) transfers fuel from the tank to the engine’s fuel injection system.
  • Fuel pump: A pump that transfers fuel from the tank to the engine’s fuel injection system via the fuel line.        
  • Fuel tank (ethanol/gasoline blend): Stores fuel on board the vehicle to power the engine.            
  • Internal combustion engine (spark-ignited): Here fuel inject into either the intake manifold or the combustion chamber, where it is combined with air, and the air/fuel mixture is ignited by the spark from a spark plug.            
  • Transmission: Transfer mechanical power from the engine and/or electric traction motor to drive the wheels.          

  Gasoline Car

  • Battery: The battery provides electricity to start the engine and power vehicle electronics/accessories.
  • Electronic control module (ECM): The ECM controls the fuel mixture, ignition timing, and emissions system.Similarly it monitors the operation of the vehicle, safeguards the engine from abuse, detects and troubleshoots problems.            
  • Exhaust system: The exhaust system channels the exhaust gases from the engine out through the tailpipe. A three-way catalyst is there to reduce engine-out emissions within the exhaust system.            
  • Fuel filler: A nozzle from a fuel dispenser attaches to the receptacle on the vehicle to fill the tank.    
  • Fuel injection system: This system introduces fuel into the engine’s combustion chambers for ignition.            
  • Fuel line: A metal tube or flexible hose (or a combination
  • ) transfers fuel from the tank to the engine’s fuel injection system.            
  • Fuel pump: A pump that transfers fuel from the tank to the engine’s fuel injection system via the fuel line.            
  • Fuel tank (gasoline): This tank stores gasoline on board the vehicle until engine require it.            
  • Internal combustion engine (spark-ignited): In this configuration, fuel inject into either the intake manifold or the combustion chamber. Then it is combined with air, and the air/fuel mixture is ignited by the spark from a spark plug.            
  • Transmission: The transmission transfers mechanical power from the engine and/or electric traction motor to drive the wheels.            

The Mechanism Behind Flex-Fuel Vehicles    

The engine of a FFV is designed to run on more than one type of fuel .Usually gasoline or a combination of fuel is stored in the same tank . When you start the engine a sensor mounted in the fuel line can detect the percentage of fuel blend . The ethanol/methanol/gasoline ratio, or the fuel’s alcohol concentration and sends a signal to an electronic control module. The electronic control module then adjusts the engine’s fuel delivery control to compensate for the different fuel mixtures.The engine then delivers the precise amount of fuel into the engine via injectors. Rest, it works similar to a conventional engine.

In order to ascertain the exact proportion of gasoline and ethanol in the fuel tank the engine management parameters should set accordingly.The virtual sensor to helps in adjusting the fueling rate. Knowledge of the ratio between the two fuels is necessary because of the different parameters of the various fuels . Nowadays, physical alcohol sensors have become more common, especially in markets with challenging emissions and on-board diagnostics requirements.

During a re filling time the sensors check the fuel tank level sensor. This helps get an approximate value for the volume of fuel . Thereby use an algorithm to allow the EMS to calculate two approximate new values of the stochiometric Air Fuel Ratio( AFR ). And then it check that the fuel added was either gasoline or a combination. On restarting it monitors the O2 sensors and looks for a perturbation in their signal. Once when the AFR is swinging in the rich or lean direction it adjusts the operating parameters gradually until it locks on to the new value and the vehicle has been ‘conditioned’. Figure shows a representation of a sensor detection system. The initial swings to the new AFR is quite rapid, but an extended period of conditioning is necessary .

Since flex fuel engines are increasingly popular they are not a miracle solution. The good news is they enable us to consume fewer fossil fuel as plant-based bio ethanol is a renewable energy source. It also burns much more cleanly, which is great for the entire environment. But flex fuels get fewer miles than gasoline-powered vehicles. Also they can be pricier and there aren’t many gas stations selling E85. Higher blending of ethanol results in higher manufacturing costs which translates to pricier vehicles. Some engine parts especially those that come in contact should be replaced with a compatible product to avoid corrosion. Despite all these ,automotive companies say that they are ready to move with government regulations on ethanol blending of E20 by 2025. Government officials have said that many popular car making companies have agreed to make flex fuel engines in coming future.

 

Stubble Burning

Paddy straw is a central field-based residue that is produced in large amounts in Asia. In reality, it could theoretically produce 187 gallons of bioethanol from the total area if the technology were available. However, an increasing proportion of this paddy straw encounters field burning, and this improper management results in high fuel prices and air pollution. For the past 25 years, conservation farming has continued to evolve. There is now less burning and, therefore, less soil cultivation and increased crop stubble retention. This trend is growing because of the need to improve water use and protect soils from erosion. As climate change is a threat to development, there is a growing interest in alternative uses of agricultural remnants.

What is stubble burning?

Crop stubble is the straw and crown of plants left on the field after harvest. Stubble consists straw and chaff discharged from the harvester. It is also known as ‘residue’ or ‘trash’. Managing this agricultural waste is one of the complex tasks that farmers must be concerned with. Usually, farmers burn stubble to manage weeds and diseases and reduce biomass to make sowing better. This is no longer a good option, as many other alternatives manage the residuals.

There are primarily two types of residues from rice cultivation that have potential in terms of energy—straw and husk. Although the technology of using rice husk is thoroughgoing in many Asian countries, paddy straw, as of now, is rarely using as a source of renewable energy. One of the principal reasons for the major use of husk is its easy procurement, i.e., it is possible at the rice mills. Collecting paddy straw is tedious, and its availability is tedious during harvest time. The collection logistics improve through baling, but the fundamental equipment is expensive and buying it is uneconomical for farmers. So technologies should develop for the efficient use of a straw to commit for the high costs involved in straw collection.

Retaining stubble than burning or cultivating, protects the soil from erosion. It also preserves soil moisture and organic matter to retain crop production. This is mainly beneficial in dry areas or dry seasons. Stubble impact many things, including the passage of equipment, penetration, soil temperature, herbicide interactions, frost severity, pests, weeds and other problems. Burning is often used as a last way to manage heavy agricultural residuals. Stubble burning contributes to global warming to a great extent. About 39 million tonnes of paddy straw are burning yearly. In The Indian state of Punjab, rice farms burn about 7 to 8 million tons of leftover plant debris. Similarly, the total national annual emission for CO2 from crop residue burning is more than 64 times the total CO2 pollution emission in Delhi.

Why do farmers choose stubble burning?

Burning paddy straw residue has risen remarkably over the past twenty years. Despite the benefits of keeping the stubble, most of the farmers opt for heavy stubble burning for the following reasons:

  • Ease of sowing and better establishment of tiny seeds like canola.
  • To make the area most inappropriate for many types of pests.
  • To manage certain weeds, mainly herbicide-resistant weed populations.
  • Burning is the cheapest and easy way to remove stubble and control weeds.
  • Reduced reliance on agricultural chemicals.
  • Provides better weed control caused due to a more even spreading of herbicides and effective incorporation of pre-emergent herbicides.
  • Less nitrogen tie-up -Nitrogen tie-up in cropping soils is only a temporary constraint as the immobilised N will be released through microbial turnover, mostly later in the crop season in spring.
  • To some extent, it results in less frost damage to crops.
  • By completely removing the stubble, only less inoculum is required for certain crop diseases.

Harmful effects of burning

  • Atmospheric pollution and climatic changes:

Open stubble burning emits many toxic pollutants into the atmosphere, which contain harmful gases like methane, carbon monoxide etc. These gases contribute a lot to the formation of smog. Stubble burning emits delicate particulate matter at high levels, which concerns people’s health. These particles can get trapped inside the lungs, ultimately leading to lung cancer. Pollution from stubble burning significantly reduced lung function and was particularly harmful to people in the surrounding area.

  • Effects on soil fertility and agricultural production:

Stubble burning affects soil fertility through the destruction of nutrients present in the soil.t also raises the soil temperature to about 42 °C, thus displacing or killing the essential microorganisms in the soil at a depth of about 2.5 cm. Thus successive fire destroys the soil’s fertility, resulting in the reduction of crop yields over time, and therefore growers have to rely on costly fertilisers.

  • Effects on human health and mortality rates:

Many studies have established the vital role of air pollution in the rising health problems, especially among children, pregnant women, elderly persons, and people with pre-existing health issues. This hazardous chemical produced as a result of burning causes problems for skin and eyes irritation, severe neurological, cardiovascular, and respiratory diseases etc. Moreover, the first and primary target of toxic substances inhaled through the air causes respiratory system disorders, cancer, or even death in extreme cases. Continuous exposure to particulate emissions may lead to an elevated cardiovascular mortality rate.

Alternatives to burning heavy stubble

There are many valuable ways to manage stubble rather than burning it and causing pollution. Some of them are :

  • Growers should focus on cutting heavy stubble and using it after harvest. This helps to shorten stubble, retain soil moisture and accelerate decomposition.
  • Inter-row sowing allows stubble to be retained when crop rows are more than 22 centimetres wide.
  • Growers may need to review stubble management decisions each year.
  • Strategic removal of stubble-it is possible to lower stubble loads if they are likely to make problems with sowing, establishment or weed management. Legume and oilseed crops produce reduce stubble loads. Their inclusion in the rotation may help to manage the risk of stubble burning.
  • Grazing-Small mobs of sheep in large paddocks often only reduce stubble loads in parts of the paddock.
  • Bailing- It is possible to remove stubbles profitably after harvest by baling straw. Baled straw has been used in animal bedding, mushroom compost and livestock feed for some years. It has other potential uses, such as for bioenergy.

Since the pollution from stubble burning has become a concern, Khaitan bioenergy has found a way to extract ethanol from it, which is a valuable fuel. Thus proper stubble management is economically beneficial to farmers and can protect the environment from severe pollution.

Biofuel production and energy generation

Recently much progress has done in the usage of stubble for biofuel production. This applies to managing agricultural stubble, which promotes cleaner air and a greener environment by preventing the release of toxic emissions by burning and indirectly reducing the use of fossil fuel-based energy. India ultimately depends on imports for automobile fuel, spending massive amounts of money for obtaining and transporting into the country. A shift from fossil fuel energy to biofuel produced from agricultural stubble is a feasible alternative. Biofuels have recently been gaining global interest due to their lower carbon footprint than fossil fuels.

Most farmers in North India are unaware of these prolific alternatives and, therefore, consider burning the best option. This necessitates extensive awareness programs to enlighten the growers about the availability of economically feasible options and the combined effects of stubble burning.

In short, despite the federal and state government’s strict policies and legislation to ban the burning practices, the activity continues in many parts of northern India, especially in Punjab, Haryana and Uttar Pradesh. Nationalistic compliance with these strategies requires effective follow-up with timely and continuous tracking everywhere. The government should compel the pulp and paper production, bioenergy and power industries to use the crop stubble as a proportion of their raw materials. This will motivate the farmers as selling the stubble will generate additional income. So an immense awareness program is necessary to notify the farmers of the environmental and economic benefits of using alternative approaches for managing the crop stubble.

International Ozone Day

What is an Ozone Layer?

The ozone layer works as a protective screen, absorbing UV rays from the sun, commonly represented as O3 and comprises three oxygen atoms. This layer is located between 15 to 30 kilometres above the Earth’s surface in the stratosphere. It produces natural UV light from the sun, reacting with molecular oxygen (O2). However, in a nutshell, we could say that ozone serves as a layer that shields harmful rays and pollutants.

Causes and effects of Ozone layer depletion

Several regularly used compounds have been discovered to be particularly harmful to the ozone layer. Halocarbons are compounds with one or more carbon atoms bonded to halogen atoms (fluorine, chlorine, bromine or iodine). Bromine-containing halocarbons typically have a substantially higher ozone-depleting potential (ODP) than chlorine-containing halocarbons. The artificial substances that have provided the majority of the chlorine and bromine for ozone depletion are methyl bromide, methyl chloroform, carbon tetrachloride, and the halons, chlorofluorocarbons (CFCs), and hydrochlorofluorocarbons families of chemicals (HCFCs).

Depletion of stratospheric ozone occurs over both hemispheres of the Earth. However, this phenomenon is less severe in the northern hemisphere (Arctic) than in the southern hemisphere (Antarctica). This is because meteorological variability is more significant over the Arctic than in the Antarctic year-to-year. Furthermore, temperatures in the stratosphere do not remain low for a long time in the Arctic, as in the case in the Antarctic.

The concentration levels of 220 Dobson Units (DU) or less (in blue in the figure) show severe ozone depletion and develop “ozone hole”. Basically, It is an area or a region of significant ozone layer thinning in high latitudes, primarily in winter, caused by the chemical action of CFCs and other atmospheric contaminants. This is only apparent in the southern hemisphere. Here, the most significant historical extent of the ozone hole – 28.4 million km2– occurred in September 2000. This area is equivalent to almost seven times the territory of the European Union (EU).

Maximum ozone hole extent over the southern hemisphere (1979-2021)

Preservation of the Ozone Layer

Hazardous chemicals emitted through aerosol sprays, refrigerants, solvents, propellants, foam-blowing agents, and other sources cause ozone layer depletion. UV radiations break down chlorofluorocarbon molecules in the stratosphere, releasing chlorine atoms. The influence of radiative forcing on the climate increases as greenhouse gas concentrations rise. The breakdown of stratospheric ozone by substances such as chlorine radicals increases UV radiation at the terrestrial level. These distinct occurrences are part of a more prominent family of global environmental changes. Scientists claim that in the early 1970s, stratospheric ozone levels in the polar regions began to decline. But the ozone’s condition has improved, according to a 2018 “Ozone Depletion Factor” measurement. Also, some of the climate change is now slowed down by continuous efforts.

World Ozone Day

Ozone Day aims to achieve the objectives of the Montreal Protocol and its amendments and promote public awareness about the importance of protecting the Ozone Layer from depletion. The ozone layer protects us from the sun’s ultraviolet radiation (UV rays). The Montreal Protocol forbids the use of substances that weaken the ozone layer with the long-term goal of eliminating them in light of new scientific and technological knowledge. Its structure is based on many categories of ozone-depleting chemicals. Nearly 100 substances across various types must be under control according to the Protocol. The Treaty lays out a timeline for phasing out the production and consumption of each class or annexe of chemicals to eliminate them.

Montreal Protocol (2022)

When the Montreal Protocol was signed in 1987, all 197 members of the United Nations voted in favour of it. The Canadian city of Montreal typically plans several special events, lectures, and seminars on September 16 every year. The United Nations General Assembly (UNGA) established International Day for preserving the Ozone Layer in 1994. The day’s primary goal is to raise awareness about the Ozone Layer’s depletion and to look for ways to protect it. On September 16th, people from all over the world will gather in Montreal to attend the speeches and seminars. Educators frequently set aside this day to teach their pupils about the Ozone layer, and many schools organise special events and activities to increase awareness.

The Montreal Protocol@35: The theme of the 2022 International Day for the Preservation of the Ozone Layer, which will be held on September 16th, is global cooperation to protect life on Earth. The theme recognises the Montreal Protocol’s broader impact on global warming and the need to act in harmony, form partnerships, and develop international collaboration to solve climate challenges and protect life on Earth for future generations.

Why is Ozone Day Important?

The ozone layer preserves life on Earth by absorbing harmful UV radiation, which is essential for life to exist on this planet. The ozone layer protects us from the sun’s ultraviolet radiation (UV rays). UV radiation from the sun causes cataracts, blindness, a weakened immune system, skin ageing, and other health issues. Direct UV radiation exposure in animals and humans promotes skin and eye cancer. UV-B rays also cause crop damage. UV-B exposure has a significant influence on plankton and zooplankton and a decrease in plant productivity which has an impact on soil erosion and the carbon cycle. Reduced plant growth, smaller leaf size, decreased blooming and photosynthesis, and lower crop quality.

How can we prevent ozone layer depletion

Here are some steps which each of us can put forward to protect the ozone layer from depletion :-

  • Consume ozone-depleting gases as little as possible.
  • Avoid burning plastics and rubber materials, which emit toxic fumes into the environment.
  • Reduce the use of smoke-emitting automobiles.
  • Try to replace hazardous cleaning products, cosmetics, hair spray, air fresheners, and other household products with non-toxic alternatives.
  • Encourage gardening and plantation to lower the risk of harmful pollutants in the atmosphere.
  • Maintain air conditioners as their malfunctioning generates CFC production.
  • Raise awareness on World Ozone Day about the significance of keeping our environment safe and healthy to protect the ozone layer.
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